Organic electrosynthesis using toluates as simple and versatile radical precursors
نویسندگان
چکیده
منابع مشابه
Organic electrosynthesis using toluates as simple and versatile radical precursors.
The electrolysis of toluate esters leads smoothly to the formation of the radical of the alkyl fragment. This property has been used to develop a new electrochemical deoxygenation reaction.
متن کاملA Crystallization-Induced Asymmetric Transformation using Racemic Phenyl Alanine Methyl Ester Derivatives as Versatile Precursors to Prepare Amino Acids
L-Tyrosine and L-Dopa are the precursors in the biological synthesis of amine neurotransmitters. On the other hand, phenylalanine as an aromatic amino acid (AAA) is a precursor in the synthesis of L-Tyrosine and L-Dopa. For some substrates such as amino acids, resolution by the formation of diastereomers offers an attractive alternative. Among different methods in this case, crystallization-ind...
متن کاملReductive electrosynthesis of crystalline metal-organic frameworks.
Electroreduction of oxoanions affords hydroxide equivalents that induce selective deposition of crystalline metal-organic frameworks (MOFs) on conductive surfaces. The method is illustrated by cathodic electrodeposition of Zn(4)O(BDC)(3) (MOF-5; BDC = 1,4-benzenedicarboxylate), which is deposited at room temperature in only 15 min under cathodic potential. Although many crystalline phases are k...
متن کاملNovel Porous Iron Molybdate Catalysts for Synthesis of Dimethoxymethane from Methanol: Metal Organic Frameworks as Precursors
As a novel performance, methanol gas conversion to dimethoxymethane (DMM) in one-step based on Fe-Mo-O (iron molybdate mixed oxides) catalysts with high surface area fabricated by metal organic frameworks (MOFs) precursors was improved. For this approach, at first, Fe(III) precursors (iron (III) 1,3,5-benzenetricarboxylate (MIL-100 (Fe) and iron terephthalate (MOF-...
متن کاملVersatile microrobotics using simple modular subunits
The realization of reconfigurable modular microrobots could aid drug delivery and microsurgery by allowing a single system to navigate diverse environments and perform multiple tasks. So far, microrobotic systems are limited by insufficient versatility; for instance, helical shapes commonly used for magnetic swimmers cannot effectively assemble and disassemble into different size and shapes. He...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Chem. Commun.
سال: 2009
ISSN: 1359-7345,1364-548X
DOI: 10.1039/b813545b